GB/T 38597-2020 English PDF (GBT38597-2020)
GB/T 38597-2020 English PDF (GBT38597-2020)
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GB/T 38597-2020: Technical requirement for low-volatile-organic-compound-content coatings product
GB/T 38597-2020
GB
NATIONAL STANDARD OF THE
PEOPLE’S REPUBLIC OF CHINA
ICS 87.040
G 51
Technical requirement for low-volatile-organic-
compound-content coatings product
ISSUED ON: MARCH 31, 2020
IMPLEMENTED ON: FEBRUARY 01, 2021
Issued by: State Administration for Market Regulation;
Standardization Administration of the People's Republic of
China.
Table of Contents
Foreword ... 3
Introduction ... 4
1 Scope ... 6
2 Normative references ... 6
3 Terms and definitions ... 7
4 Requirements ... 8
5 Test methods ... 12
6 Rules for determination ... 14
7 Packaging marks ... 14
8 Implementation of standard... 15
Annex A (normative) Determination of moisture content - Gas chromatography
... 16
Bibliography ... 20
Foreword
This Standard was drafted in accordance with the rules given in GB/T 1.1-2009.
This Standard was proposed by China Petroleum and Chemical Industry
Federation.
This Standard shall be under the jurisdiction of National Technical Committee
on Coatings and Pigments of Standardization Administration of China (SAC/TC
5).
The drafting organizations of this Standard: Environmental Planning Institute,
Ministry of Ecology and Environment, China Coatings Industry Association,
China Petroleum and Chemical Industry Federation, CNOOC Changzhou
Coating Chemical Research Institute Co., Ltd.
Main drafters of this Standard: Wang Ning, Ji Junhong, Li Li, Yang Jianhai, Xue
Yan, Tang Ying, Su Chunhai, Ning Miao, Wang Zhen.
Technical requirement for low-volatile-organic-
compound-content coatings product
1 Scope
This Standard specifies requirements, test methods, rules for determination,
packaging marks, implementation of standard for low-volatile-organic-
compound-content coatings product.
This Standard is applicable to the determination of low-volatile-organic-
compound-content coatings product.
2 Normative references
The following referenced documents are indispensable for the application of
this document. For dated references, only the edition cited applies. For undated
references, the latest edition of the referenced document (including any
amendments) applies.
GB/T 1725-2007, Paints varnishes and plastics - Determination of non-
volatile-matter content
GB/T 3186, Paints varnishes and raw materials for paints and varnishes -
Sampling
GB/T 5206-2015, Paints and varnishes - Terms and definitions
GB/T 6682-2008, Water for analytical laboratory use - Specification and test
methods
GB/T 6750-2007, Paints and varnishes - Determination of density -
Pycnometer method
GB/T 8170-2008, Rules of rounding off for numerical values and expression
and judgement of limiting values
GB/T 9750, Marks for package of coating products
GB/T 23985-2009, Paints and varnishes - Determination of volatile organic
compound (VOC) content - Difference method
GB/T 23986-2009, Paints and varnishes - Determination of volatile organic
compound (VOC) content - Gas-chromatographic method
GB/T 34675-2017, Determination of volatile organic compound (VOC)
content in radiation curable coatings
GB/T 34682-2017, Determination of volatile organic compound (VOC)
content in reactive diluent containing coatings
3 Terms and definitions
For the purposes of this document, the terms and definitions defined in GB/T
5206-2015 as well as the followings apply. For ease of use, some terms and
definitions in GB/T 5206-2015 are listed repeatedly below.
3.1 low-volatile-organic-compound-content coatings product
The coating product that under application condition, the quality of the volatile
organic compounds present in the coating products meets the volatile organic
compound content limit requirements of the corresponding products in this
Standard.
3.2 coating material
Liquid, paste or powder product. When it is applied to the substrate, it can form
a coating with protection, decoration and/or other special functions.
[GB/T 5206-2015, definition 2.51]
3.3 volatile organic compound; VOC
The organic compound participating in atmospheric photochemical reactions,
or organic compound determined according to relevant regulations.
3.4 volatile organic compound content; VOC content
The mass of the volatile organic compounds presents in the paint measured
under the specified conditions.
[GB/T 5206-2015, definition 2.271]
3.5 application condition
The state that when the construction method and construction conditions meet
the requirements in the corresponding product technical specification, after all
the components of the product are mixed, construction can be carried out.
5.2.2.2 VOC content in water-based coating
5.2.2.2.1 VOC content in architectural wall coatings, wood coatings, floor
coatings, waterproof coatings, and road marking coatings
Carry out according to the regulations of GB/T 23986-2009. The
chromatographic column adopts a medium-polarity column (6% is cyanopropyl
phenyl / 94% is polydimethylsiloxane capillary column). The marked substance
is diethyl adipate. Weigh about 1g of sample. The moisture content is
determined in accordance with the provisions of Annex A. The VOC content is
calculated according to 10.4 in GB/T 23986-2009.
5.2.2.2.2 VOC content in other water-based coatings
First, determine the moisture content in the water-based coating according to
the provisions of Annex A.
If the moisture content in the coating is greater than or equal to 70% (mass
fraction), it shall be carried out in accordance with the provisions of GB/T 23986-
2009. The chromatographic column adopts a medium-polarity column (6% is
cyanopropyl phenyl / 94% is polydimethylsiloxane capillary column). The
marked substance is diethyl adipate. Weigh about 1g of sample. The VOC
content is calculated according to 10.4 in GB/T 23986-2009.
If the moisture content in the coating is less than 70% (mass fraction), it shall
be carried out according to the regulations of GB/T 23985-2009. The non-
volatile content shall be carried out in accordance with the regulations of GB/T
1725-2007. Weigh about 1g of sample. Bake at (105±2)°C for 1h. The VOC
content is calculated according to 8.4 in GB/T 23985-2009.
5.2.2.3 VOC content in solvent-based coatings
Solvent-based coatings without reactive diluents and water shall be carried out
in accordance with the provisions of GB/T 23985-2009. The non-volatile content
shall be carried out in accordance with the regulations of GB/T 1725-2007.
Weigh about 1g of sample. Bake at (105±2)°C for 1h. Do not measure moisture
content. Set the moisture content as zero. The calculation of VOC content in
solvent-based coatings without reactive diluent and water is carried out
according to 8.3 of GB/T 23985-2009.
Solvent-based coatings containing reactive diluents shall be carried out in
accordance with 5.2.2.4.
Solvent-based coatings intentionally added with water shall be carried out in
accordance with the provisions of GB/T 23985-2009. The non-volatile content
shall be carried out in accordance with the regulations of GB/T 1725-2007.
Weigh about 1g of sample. Bake at (105±2)°C for 1h. The moisture content is
determined in accordance with the provisions of Annex A. The calculation of
VOC content is carried out according to 8.4 of GB/T 23985-2009.
5.2.2.4 VOC content in solvent-free paint
Carry out according to GB/T 34682-2017. The storage time when determining
the non-volatile content is the standard test environment [temperature...
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Historical versions: GB/T 38597-2020
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GB/T 38597-2020: Technical requirement for low-volatile-organic-compound-content coatings product
GB/T 38597-2020
GB
NATIONAL STANDARD OF THE
PEOPLE’S REPUBLIC OF CHINA
ICS 87.040
G 51
Technical requirement for low-volatile-organic-
compound-content coatings product
ISSUED ON: MARCH 31, 2020
IMPLEMENTED ON: FEBRUARY 01, 2021
Issued by: State Administration for Market Regulation;
Standardization Administration of the People's Republic of
China.
Table of Contents
Foreword ... 3
Introduction ... 4
1 Scope ... 6
2 Normative references ... 6
3 Terms and definitions ... 7
4 Requirements ... 8
5 Test methods ... 12
6 Rules for determination ... 14
7 Packaging marks ... 14
8 Implementation of standard... 15
Annex A (normative) Determination of moisture content - Gas chromatography
... 16
Bibliography ... 20
Foreword
This Standard was drafted in accordance with the rules given in GB/T 1.1-2009.
This Standard was proposed by China Petroleum and Chemical Industry
Federation.
This Standard shall be under the jurisdiction of National Technical Committee
on Coatings and Pigments of Standardization Administration of China (SAC/TC
5).
The drafting organizations of this Standard: Environmental Planning Institute,
Ministry of Ecology and Environment, China Coatings Industry Association,
China Petroleum and Chemical Industry Federation, CNOOC Changzhou
Coating Chemical Research Institute Co., Ltd.
Main drafters of this Standard: Wang Ning, Ji Junhong, Li Li, Yang Jianhai, Xue
Yan, Tang Ying, Su Chunhai, Ning Miao, Wang Zhen.
Technical requirement for low-volatile-organic-
compound-content coatings product
1 Scope
This Standard specifies requirements, test methods, rules for determination,
packaging marks, implementation of standard for low-volatile-organic-
compound-content coatings product.
This Standard is applicable to the determination of low-volatile-organic-
compound-content coatings product.
2 Normative references
The following referenced documents are indispensable for the application of
this document. For dated references, only the edition cited applies. For undated
references, the latest edition of the referenced document (including any
amendments) applies.
GB/T 1725-2007, Paints varnishes and plastics - Determination of non-
volatile-matter content
GB/T 3186, Paints varnishes and raw materials for paints and varnishes -
Sampling
GB/T 5206-2015, Paints and varnishes - Terms and definitions
GB/T 6682-2008, Water for analytical laboratory use - Specification and test
methods
GB/T 6750-2007, Paints and varnishes - Determination of density -
Pycnometer method
GB/T 8170-2008, Rules of rounding off for numerical values and expression
and judgement of limiting values
GB/T 9750, Marks for package of coating products
GB/T 23985-2009, Paints and varnishes - Determination of volatile organic
compound (VOC) content - Difference method
GB/T 23986-2009, Paints and varnishes - Determination of volatile organic
compound (VOC) content - Gas-chromatographic method
GB/T 34675-2017, Determination of volatile organic compound (VOC)
content in radiation curable coatings
GB/T 34682-2017, Determination of volatile organic compound (VOC)
content in reactive diluent containing coatings
3 Terms and definitions
For the purposes of this document, the terms and definitions defined in GB/T
5206-2015 as well as the followings apply. For ease of use, some terms and
definitions in GB/T 5206-2015 are listed repeatedly below.
3.1 low-volatile-organic-compound-content coatings product
The coating product that under application condition, the quality of the volatile
organic compounds present in the coating products meets the volatile organic
compound content limit requirements of the corresponding products in this
Standard.
3.2 coating material
Liquid, paste or powder product. When it is applied to the substrate, it can form
a coating with protection, decoration and/or other special functions.
[GB/T 5206-2015, definition 2.51]
3.3 volatile organic compound; VOC
The organic compound participating in atmospheric photochemical reactions,
or organic compound determined according to relevant regulations.
3.4 volatile organic compound content; VOC content
The mass of the volatile organic compounds presents in the paint measured
under the specified conditions.
[GB/T 5206-2015, definition 2.271]
3.5 application condition
The state that when the construction method and construction conditions meet
the requirements in the corresponding product technical specification, after all
the components of the product are mixed, construction can be carried out.
5.2.2.2 VOC content in water-based coating
5.2.2.2.1 VOC content in architectural wall coatings, wood coatings, floor
coatings, waterproof coatings, and road marking coatings
Carry out according to the regulations of GB/T 23986-2009. The
chromatographic column adopts a medium-polarity column (6% is cyanopropyl
phenyl / 94% is polydimethylsiloxane capillary column). The marked substance
is diethyl adipate. Weigh about 1g of sample. The moisture content is
determined in accordance with the provisions of Annex A. The VOC content is
calculated according to 10.4 in GB/T 23986-2009.
5.2.2.2.2 VOC content in other water-based coatings
First, determine the moisture content in the water-based coating according to
the provisions of Annex A.
If the moisture content in the coating is greater than or equal to 70% (mass
fraction), it shall be carried out in accordance with the provisions of GB/T 23986-
2009. The chromatographic column adopts a medium-polarity column (6% is
cyanopropyl phenyl / 94% is polydimethylsiloxane capillary column). The
marked substance is diethyl adipate. Weigh about 1g of sample. The VOC
content is calculated according to 10.4 in GB/T 23986-2009.
If the moisture content in the coating is less than 70% (mass fraction), it shall
be carried out according to the regulations of GB/T 23985-2009. The non-
volatile content shall be carried out in accordance with the regulations of GB/T
1725-2007. Weigh about 1g of sample. Bake at (105±2)°C for 1h. The VOC
content is calculated according to 8.4 in GB/T 23985-2009.
5.2.2.3 VOC content in solvent-based coatings
Solvent-based coatings without reactive diluents and water shall be carried out
in accordance with the provisions of GB/T 23985-2009. The non-volatile content
shall be carried out in accordance with the regulations of GB/T 1725-2007.
Weigh about 1g of sample. Bake at (105±2)°C for 1h. Do not measure moisture
content. Set the moisture content as zero. The calculation of VOC content in
solvent-based coatings without reactive diluent and water is carried out
according to 8.3 of GB/T 23985-2009.
Solvent-based coatings containing reactive diluents shall be carried out in
accordance with 5.2.2.4.
Solvent-based coatings intentionally added with water shall be carried out in
accordance with the provisions of GB/T 23985-2009. The non-volatile content
shall be carried out in accordance with the regulations of GB/T 1725-2007.
Weigh about 1g of sample. Bake at (105±2)°C for 1h. The moisture content is
determined in accordance with the provisions of Annex A. The calculation of
VOC content is carried out according to 8.4 of GB/T 23985-2009.
5.2.2.4 VOC content in solvent-free paint
Carry out according to GB/T 34682-2017. The storage time when determining
the non-volatile content is the standard test environment [temperature...